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复合侵蚀环境下含石灰石粉砂浆的劣化行为

李鑫 胡宁宁 饶美娟  刘数华   

  • 出版日期:2015-05-15 发布日期:2015-05-15

Study on deteriorated behavior of mortar containing limestone powder under complex erosion environment

  • Online:2015-05-15 Published:2015-05-15

摘要: 为研究混凝土在掺入石灰石粉后的抗复合侵蚀性能,采用不同含量的石灰石粉制备水泥净浆及砂浆试件,将其浸泡在盐酸与硫酸镁复合侵蚀溶液中展开试验。运用pH测试仪测试溶液的pH值变化,并通过强度试验及XRD能谱分析,观测不同侵蚀时间下水泥砂浆试件强度和侵蚀产物的变化,揭示石灰石粉对水泥砂浆抗盐酸与硫酸镁复合侵蚀性能的影响。结果表明:前期侵蚀溶液的pH变化较快,后期较慢;在侵蚀28d之前,砂浆试件的强度呈上升趋势,28 d之后随着石灰石粉掺量的增加,强度呈下降趋势。侵蚀过程中主要表现为酸与氢氧化钙和碳酸钙的反应,镁离子侵蚀并不明显;由于硫酸根离子的存在,侵蚀过程中会生成石膏,可延缓侵蚀进程。

关键词: pH值, 石灰石粉, 硫酸镁, 盐酸, 复合侵蚀

Abstract:

To research the anti-erosion performance of mortar containing the limestone powder, the cement pastes and mortars with different contents of limestone powder were prepared and soaked into the hydrochloric acid and magnesium sulfate complex erosion solution. The change of pH value of solution was tested by pH tester, while the strength test and X-ray Diffraction were carried out to study the variation of the strength of the mortar containing limestone powder and the erosion products under complex erosion time. The testing results show that the pH changes rapidly at the early stage and later slowly. Before 28 d erosion, the strength of the mortar increases, then declines with the increasing dosage of limestone powder after 28 d erosion. The process of erosion is acid reactions with calcium hydroxide and calcium carbonate while the erosion of magnesium ions is not obvious. Furthermore, because of the existence of sulfate ion, the gypsum is generated, which slows down the erosion process.

Key words: limestone powder, magnesium sulfate, hydrochloric acid, complex erosion