人民长江 ›› 2023, Vol. 54 ›› Issue (3): 205-209.doi: 10.16232/j.cnki.1001-4179.2023.03.031

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单组份聚脲涂层材料耐紫外性能研究

梁慧;熊泽斌;王媛怡;周中行;   

  • 出版日期:2023-03-28 发布日期:2023-04-03

Study on UV resistance of monocomponent polyurea coating material

LIANG Hui XIONG Zebin WANG Yuanyi ZHOU Zhonghang   

  • Online:2023-03-28 Published:2023-04-03

摘要: 在高海拔地区,普通高分子类水工混凝土表面防护涂层材料由于受到强烈紫外辐射,易出现变色、粉化、龟裂等现象,服役寿命明显缩短。选取一种综合性能较好的单组份聚脲材料,通过设计紫外辐射-冷凝加速老化室内模拟试验,开展了聚脲材料的拉伸性能、聚脲/砂浆体系的粘接性能测试,并利用扫描电镜SEM、红外光谱等手段分析了涂层的微观形貌和结构变化。结果表明:紫外辐射-冷凝老化过程中,聚脲材料中高分子发生分解导致涂层表面产生粉化,表面的N-H、C-H、-OH化学键发生变化,粘接强度、拉伸强度、断裂伸长率与老化时间呈指数相关。研究成果可为提高聚脲涂层耐紫外性能、更准确地预测聚脲类水工混凝土防护涂层的使用寿命提供一定的理论依据。

关键词: 单组份聚脲;防护涂层;紫外辐射;高海拔地区;

Abstract: In high altitude areas, the ordinary polymer surface protective coating materials for hydraulic concrete are easy to discoloration, pulverization, cracking because of strong ultraviolet radiation and their service lives are obviously shorten.In this paper, a monocomponent polyurea material with better comprehensive performance was selected, and the indoor simulation test of ultraviolet radiation-condensation accelerated aging was designed.The tensile properties of polyurea material and the bonding properties of polyurea/mortar system were tested.The changes of microstructure and the coating structure were analyzed by scanning electron microscopy(SEM) and infrared spectroscopy.It was found that during the ultraviolet radiation-condensation aging process, the polymer in the polyurea material decomposed, resulting in the pulverization of the coating surface, and the chemical bonds of N-H,C-H and-OH on the surface changed.The bonding strength, tensile strength and elongation at break were exponentially correlated with the aging time.The research results provide a theoretical basis for improving the UV resistance of polyurea coatings and more accurately predict the service life of polyurea protective coatings for hydraulic concrete.

Key words: monocomponent polyurea; protective coating; ultraviolet radiation; high altitude area;